Its like blossom end rot on tomatoes, uneven temperatures....high in the day cool at night and uneven watering because of it

Hopefully not all are affected
You could try removing some if thats the case and ripen them on a sunny windowsill

I grow peppers rather than chilli and guess thesame applies

Thanks. They are growing in my porch that can be very hot during the day. I water them every morning at the same time so must be down to the temperature changes. Thanks again

You're welcome
Hopefully some will be ok, can you cover them at night?.....